首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   895篇
  免费   62篇
  国内免费   18篇
化学   669篇
晶体学   1篇
力学   54篇
数学   108篇
物理学   143篇
  2024年   1篇
  2023年   2篇
  2022年   18篇
  2021年   29篇
  2020年   43篇
  2019年   59篇
  2018年   52篇
  2017年   46篇
  2016年   95篇
  2015年   52篇
  2014年   49篇
  2013年   143篇
  2012年   77篇
  2011年   72篇
  2010年   57篇
  2009年   43篇
  2008年   33篇
  2007年   39篇
  2006年   12篇
  2005年   13篇
  2004年   10篇
  2003年   8篇
  2002年   6篇
  2001年   3篇
  2000年   1篇
  1997年   1篇
  1996年   1篇
  1995年   1篇
  1990年   1篇
  1989年   2篇
  1988年   1篇
  1987年   1篇
  1986年   1篇
  1985年   1篇
  1984年   1篇
  1980年   1篇
排序方式: 共有975条查询结果,搜索用时 62 毫秒
71.
The quantum trajectory renders the optimal estimation of quantum state. It is a classical Itô stochastic differential equation. The Lyapunov global stabilization problem is solved for squeezed noise quantum trajectory. Lyapunov control stabilizes the quantum system toward one eigenstate. A two-level bistable quantum system is simulated as an example.  相似文献   
72.
<正>The addition of 2,4-dihydroxyaceto(and benzo)phenone to propiolic ester is catalyzed by triphenylphosphine or tert-butyl isocyanide to form O-vinyl aryl derivatives in fairly good yields.  相似文献   
73.
Using Auslander’s G-dimension, we assign a numerical invariant to any group Γ. It provides a refinement of the cohomological dimension and fits well into the well-known hierarchy of dimensions assigned already to Γ. We study this dimension and show its power in reflecting the properties of the underlying group. We also discuss its connections to relative and Tate cohomology of groups.  相似文献   
74.
Russian Journal of Applied Chemistry - Titanium dioxide (TiO2) is widely used in the paint industry as a white pigment. To reduce the high cost of TiO2, mineral fillers such as different calcites...  相似文献   
75.
A simple and practical procedure for synthesis of 2-arylbenzimidazoles by a one-pot condensation of o-phenylenediamine with aromatic aldehydes in the presence of a catalytic amount of M(NO3)2·6H2O (M = Mn, Fe, Co, Ni, Cu) in ethanol at room temperature is described. Major advantages of this practical procedure are use of a readily available catalyst, high yields, short reaction times, and simplicity of the reaction and workup.  相似文献   
76.
The objective of this study is to investigate the possibility of using Co-CNTs as a green reaction medium and a catalyst for the cyclo-condensation of o-aminobenzamide with various aldehydes. This inexpensive, non-toxic, and readily available catalyst efficiently catalyzes the above condensation for the synthesis of 2-aryl-2,3-dihydroquinazolin-4(1H)-ones. Compared to the classical reaction, this is a simple, highly yielding, time saving, and environmentally friendly method.  相似文献   
77.
JPC – Journal of Planar Chromatography – Modern TLC - In this study we conducted in-vitro incubation of whole-tissue homogenate of young adult guinea pig heart, kidney, testis, and...  相似文献   
78.
In this article simultaneous effects of external electric field and spin-orbit interaction on the linear and the nonlinear optical properties of a cubic quantum dot are studied. Based on the non- degenerate perturbation method, energy eigenvalues and eigenfunctions of the system under the influence of spin-orbit interaction are calculated. Furthermore, the linear and the nonlinear optical absorption coefficients and refractive index changes are obtained using the compact density matrix approach and iterative method. Our results show that, due to the spin-orbit interaction, resonant peak values of the optical absorption coefficients and refractive index changes decrease and occur at lower values of the incident photon energy. The variation of these optical parameters depend on the spin-orbit interaction strength, dot dimensions and external electric field.  相似文献   
79.
The approach of this work was to study the capability of graphene‐based materials in the field of biological sample preparation. A polypyrrole/graphene composite was synthesized and characterized. The potential of the nanocomposite was investigated as a sorbent in dispersive solid‐phase extraction followed by high‐performance liquid chromatography with UV detection for vancomycin as a model drug. The effect of different parameters influencing extraction efficiency such as sample pH and sample volume, ionic strength, extraction time, type, and volume of desorption solvent and desorption time were investigated. A comparison study was also conducted between polypyrrole/graphene and some different novel and classic sorbents. Under optimized conditions, the calibration curve for vancomycin showed linearity in the range of 0.05–10 μg/mL. In addition, limits of detection, and quantification were 0.003 and 0.01 μg/mL, respectively. The intraday and interday relative standard deviations at a concentration of 0.05 μg/mL (n = 3) were 1.6 and 2.1%, respectively. Furthermore, the proposed method was successfully applied for the determination of vancomycin in plasma and urine samples. The relative recoveries indicated the feasibility of graphene‐based sorbents in biological sample analysis.  相似文献   
80.
A supported carbon material is shown to be a highly efficient, eco-friendly and recyclable solid acid catalyst for the Biginelli reaction of aldehyde, β-ketoester and urea or thiourea under microwave irradiation in the absence of solvent. This method offers significant advantages such as efficiency, the excellent yield, avoidance of the organic solvents, mild reaction conditions, easy separation and simple operation. In addition, because of employing microwave as heating source and reducing use of organic solvents, this novel method emerges as a green-approach leading to less harmful residues. Furthermore, a mechanism was proposed to rationalize the reaction and the role of NiO–MWCNTs was also investigated in these transformations.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号